This is such an interesting question actually. I voted for the money. It would not solve all my problems, but it would solve enough of them to change the cost/benefit analysis of continuing to live. I would no longer be facing homelessness. I could move to a country more in line with my values. Most importantly, I could pay the $30,000+ to fix my teeth and no longer be forced to literally hide from everyone I know. I don't know, it sounds pretty good. It's not like depression or addiction magically disappear when you get money, but at least it would provide resources that one could use to concretely improve their situation.
On the other hand, a lot of wealthy people don't seem very happy either, and many seem way to concerned about money. To me, the only reason for desiring wealth is that you no longer have to think about money.
Like I totally don't get someone who has $100 million, and feels like, that's not enough, and they spend all their time trying to get more. There has to be something seriously wrong with those people. But maybe that's why they aren't happy -- because there's no amount of wealth which they have mentally designated as "enough."
Anyway if it turns out you still prefer to check out early, having access to such resources would significantly expand one's options and make the process less frustrating. Of course, most of the money would probably be given away, it seems like a ghastly thing to just spend $100mil on yourself because you can, starting silly collections of rare expensive objects or some other such contemptible nonsense. god people suck.
Hmm... maybe the "die in your sleep" option is actually better. Because after you get $100mil, everyone will want to be your friend, which could actually result in even greater isolation than before. you will become a target for all sorts of scammers and dishonest people trying to climb the social ladder. I don't know. This question is a lot more complicated than it sounds. I voted for money but I think I'm actually undecided.