Many moons ago, one could walk into your local big box mart and buy a Helium party balloon tank. It would be near 99% Helium. Party kids would inhale it to make funny sounds. They would also die . The parents would file wrongfull death lawsuits. So the later tanks were now filled with 80% Helium and 20% Oxygen. No more wrongfull death lawsuits. Because the air is 20.9% Oxygen, these tanks will not kill you. If your goal is to die, well Houston we have a problem.. 99% Helium should kill.