Depends on how quickly you want to die... and what sources you believe. I've read that 800 PPM kills in two to three hours, 12,000 PPM within 3 minutes.
The CDC says that the low lethal concentration in humans is 4,000 or 5,000 PPM, while the
BSI and OSI have different numbers:
The British Standards Institution (BSI 1989) published the following concentration–time combinations as lethal exposures to CO (used for hazard estimation in fires): 40,000 ppm × 2 min, 16,000 ppm × 5 min, 8,000 ppm × 10 min, 3,000 ppm × 30 min and 1,500 ppm × 60 min. The International Standard Organization (ISO) published lethal exposure concentrations of 12,000-16,000 ppm for 5 min and 2,500-4,000 ppm for 30 min (for an adult engaged in light activity)